AIEEE 2007 Quarter Test Paper

by Mr. Arun Kulshrestha

Ques 1 -12 [1.5 marks] / Ques 13-25 [3 marks] / Ques 26-40 x 4.5 marks
-ve marks are one third
Test duration 2 hour

1.Which of the following compounds can exhibit tautomerism? [1] [2] [3] [4] 2.Tautomerism is not exhibited by: (1) C6H5-CH=CH-OH (2) (3) (4) 3.Which will show tautomerism: [1] [2] [3] [4] 4.Tautomerism is exhibited by (1) (CH3)3CNO (2) (CH3)2NH (3) R3CNO2 (4) RCH2NO2 5.Total possible structural isomers(not stereo) of C4H6 are: (1) 4 (2) 6 (3) 9 (4) 12 6.Increasing order of expected enol content (1) CH3COCH2CHO>-CH3COCH3 CH3CHO>CH3COCH2COCH3 (2) CH3COCH2COCH3> CH3COCH2CHO>CH3COCH3>CH3CHO (3) CH3CHO>CH3COCH3 >CH3COCH2CHO>CH3COCH2COCH3 (4) CH3COCH3>CH3COCH2COCH3 >CH3CHO>CH3COCH2CHO 7.Increasing order of expected keto content (1) CH3COC2H5>CH3CHO >CH3COCH3>CH3COCH2COCH3 (2) CH3COCH3>CH3CHO >CH3COC2H5>CH3COCH2COCH3 (3) CH3CHO>CH3COC2H5 >CH3COCH3>CH3COCH2COCH3 (4) CH3COCH2COCH3>CH3CHO >CH3COCH3>CH3COC2H5 8. Hydrogenation of the above compound in the presence of posioned palladium catalyst gives: [1] an optically active compound [2] an optically inactive compound [3] a reacemic mixture [4] a diastereomeric mixture 9.Which of the following is an example of substitution reaction: [1] [2] [3] [4] None of the above 10.List the following alkoxide nucleophile in decreasing order of their SN2 reactivity: (a) Me3CO- (b) MeO- (c) MeCH2O- (d) Me2CHo- (e) [1] b>c>e>d>a [2] e>c>b>a>d [3] a>e>b>c>d [4] c>e>a>b>c 11.Which will not undergo substitution bySN1: (1) CH2X (2) (3) (4) 12.Identify the set of reagents/reaction conditions 'X' and 'Y' in the following set of transformations: (1) X=dil.aq.NaOH,20oC,Y=HBr (2) X=conc.alcoholic NaOH,80oC,Y=HBr,CH3COOH,20oC (3) X=dil.aq.NaOH,20oC,Y=Br2,CHCl3,0oC (4) X=conc.alc.NaOH,80oC,Y=Br2,CHCl3,0oC 13. The nodal plane in the-bond of ethene is lacated in: (1) The Molecular (2) A plane parallel to the molecular plane (3) a plane perpendicular to the molecular plane which bisects the carbon-carbon sigma bond at right angle. (4) a plane perpendicular to the molecular plane which contains the carbon-carbon sigma bond. 14. (CH3)4+N is neither an electrophile or a nucleophile because it: (1) Does not have electron pair for donation as well as cannot attract electron pair (2) Neither has electron pair available for donation nor can accommodateelectron since all shell of N are fully occupied. (3) Can act as Lewis acid or base. (4) none of these 15. In the dehydration reaction: the hybridization state of carbon changes from: [1] sp3 to sp2 [2] sp to sp [3] sp2 to sp [4] sp to sp3 16. A compound X (C5H8) reacts with ammoniacal AgNO3 to give a white precipitate,and on oxidation with hot alkaline KMnO4 gives the acid,(CH3)2CHCOOH.Therefore,X is: (1) CH2=CHCH=CHCH3 (2) CH3(CH2)2C CH (3) (CH3)2 CH-C CH (4) (CH3)2C=C=CH2 17.What is the decreasing order of the strength of the bases OH-,NH2-,H-C C- and CH3CH2-? (1)CH3-CH2-> NH2-> H-C C-> OH- (2)H-C C-> CH3-CH2-> NH2-> OH- (3)OH-> NH2-> HC C-> CH3-CH2- (4)NH2-> H-C C-> OH-> CH3-CH2- 18.Water can be added across a triple bond in the presence of : (1) acidic medium (2) alkaline medium (3) neutral medium (4) acid and HgSO4 19. Among the following,the compound that can be most readily sulphonated is: (1) benzene (2) nitrobenzene (3) toluene (4) chlorobenzene 20.Which of the following reagents cannot be used as the basis for a simple chemical test for distinbuishing but-1-ene from CH3CH2CH2CH2OH? (1) Br2/CCl4 (2) Dilute aqueous KMnO4 (3) CrO3/aqueous H2SO4 (4) Na in liquid NH3 21. Benzyl chloride (C6H5CH2Cl)can be prepared from toluene by chlorination with: (1) SO2Cl2 (2) SOCl2 (3) Cl2 (4) NaOCl 22.Which of the following reactions are not expected to give in yields of more than 50%? [1] [2] [3] [4] None of these 23. Which of the following will give trans-diols [1] [2] [3] [4] 24. The final in the following sequence of reaction is: (a) CH2=CH-CH=CH2 (b) HC C-CH3 (c) CH2=CH-CH3 (d) CH-CH2-CH3 25. Which of the following orders regarding the acidity of aromatic acids is correct? (1) p-nitrobenzoic acid <>p-anthranilic acid (2) p-nitrobenzoic acid > benzoic acid > p-anthranilic acid (3) p-nitrobenzoic acid > benzoic acid < p-anthranilic acid (4) p-nitrobenzoic acid <> p-anthranilic acid 26.Which of the following are correct? [1] [2] [3] [4] 27. [1] [2] [3] [4] 28.The following reaction is called (1) Michael addition reaction (2) Diels-Alcr reaction (3) Wolff-Kishner reaction (4) None of above 29. Nitrobenzene can be prepared from benzene by using a mixture of concentrated HNO3 and concentrated H2SO4.In the nitrating mixture,HNO3 acts as: [1] base [2] acid [3] reducing agent [4] catalyst 30.Which of the following structures will not have 4electrons? I II III IV (1) I (2) II (3) III (4) IV 31. The most strained cycloalkane is: (1) Cyclopropane (2) Cyclobutane (3) Cyclopentane (4) Cyclohexane 32.Among the following statements on the nitration of aromatic compounds,the false one is: [1]The rate of nitration of benzene is almost the same as that of hexadeuterobenzene [2]The rate of nitration of toluene is greater than that of benzene [3]The rate of nitration of benzene is greater than that of hexadeuterobenzene [4]Nitration is an electrophilic substitution reaction. 33.Which of the following conpounds will exhibit geometrical isomerism? [1] But-1-ene [2] Oxime of benzaldehyde [3] Oxime of acetone [4] Both (b) and (c) 34. The halogen which is more reactive in the halogenation of alkanes in sunlight is: (1) Chlorine (2) Bromine (3) Iodine (4) All are equal 35.The reduction of an alkyne to alkane using lithium metal in liquid ammonia as solvent results into: [1] cis addition of hydrogen atoms [2] trans addition of hydrogen atoms [3] Both cis and trans additions of hydrogen atoms.The relative amount of the two depends on temperature. [4] Both cis and trans additions of hydrogen atoms.The relative amount depend on the nature of alkyne. 36.Which cycloalkane has the lowest heat of combustion per CH2 group? [1] [2] [3] [4] 37.Which of the following will give three mono-bromo derivatives? [1] CH3CH2CH2CH(CH3)CH3 [2] CH3CH2C(CH3)2CH3 [3] CH3CH(CH3)CH(CH3)CH3 [4] All can give 38.The addition of HBr to an alkene in the presence of peroxide is the example of: [1] electrophilic addition reaction [2] nucleophilic addition reaction [3] free radical addition reaction [4] the formation of carbonation as an intermediate 39.The major product obtained in the reaction is expected to be : (1) (2) (3) (4) 40.The treatment of with NalO4 or boiling KMnO4 produces: [1]CH3COCH3+CH3COOH [2]CH3COCH3+CH3CHO [3]CH3CHO+CO2 [4]CH3COCH3 only 41.What are the products obtained by ozonolysis of RCH=CR1R2 [1] R1CH2CH2R2 [2] R2CO [3] R1COR2 [4] none of these 42.Which of the following compounds do not exhibit geometrical isomerism? (1)CH3CH=CH-COOH (2)Br-CH=CH-Br (3)C6H5CH=NOH (4) 43. Choose the compound which is not a nucleophile: [1] :OH- [2] :CN- [3] :C-CR [4] :CCl2 44. Which of the following order regarding the acidity of aromatic acids is correct? (1) benzoic acid< p-toluic acid< p- hydroxybenzoic acid (2) benzoic acid> p-toluic acid> p- hydroxybenzoic acid (3) benzoic acid> p-toluic acid< p- hydroxybenzoic acid (4) benzoic acid<> p- hydroxybenzoic acid 45. The treatment of benzene with benzoyl chloride in the presence of AlCl3 gives: (1) benzaldehyde (2) benzophenone (3) diphenyl (4) cyclohexane 46.The conversation can be effected using: [1] Br2/CCl4 [2] Br2/H2O [3] Br2/Fe [4] Br/benzoyl peroxide 47.Methane is obtained when: [1] sodium propionate is heated with sodalime [2] idomethane is reduced [3] magnesium carbide reacts with water [4] potassium acetate is electrolysed 48.1,2-dimethylcyclopentane can be represented as I,II and III. 49.Which of the following are cumulative dienes? [1]CH3-CH=C=CH-CH3 [2]CH2=CH-CH=CH2 [3]CH2=CH-CH2-CH=CH2 [4]None of these 50.Which of the following is Wurtz-Fittig reaction ? [1] [2] [3] [4] 51.Orbital angular momentum of an electron in 2s orbital is - [1] [2] zero [3] [4] 52.A Mo atom in its ground state has a 4d5 5s1 and a Ag atom 4d10 5s1 configuration.This is because a shell which is half filled or completely filled is particularly: [1] strongly exchange destabilised [2] weakly exchange stabilised [3] weakly exchange destabilised [4] strongly exchange stabilised 53.An f-shell containing 6 unpaired electron have no. of exchange [1] 6 [2] 9 [3] 12 [4] 15 54. Choose the arrangement which show the increasing value of e/m for e,p,n and particle: [1] n< [2] e [3] n [4] p 55.In which of the following orbital probability of finding electron in XY plane will be zero [1] pz [2] dyz [3] dzx [4] px 56.After np6 electronic configuration,the next orbital filled will be: [1] (n+1)d [2] (n+1)s [3] (n+1)f [4] none of the above 57.Which of the following transitions are not allowed in the normal electronic emission spectrum of an atom? [1] 2s Is [2] 2p Is [3] 3d 4p [4] 5p 3s 58.The de Broglie wavelength relates to applied voltage as : [1] [2] [3] [4] both (b) and (c) 59. The line spectra of two elements are not identical because: [1] The elements do not have the same number of neutrons [2] They have different mass numbers [3] Their outermost electrons are different energy levels [4] all of the above 60.Four different sets of quantum numbers for 4 electrons are given below: e1 = 4,0,0- ,e2 = 3,1,1,- e3 = 3,2,2+ ,e4 = 3,0,0,+ The order of energy of e1,e2,e3 and e4 is: [1] e1>e2>e3>e4 [2] e4>e3>e2>e1 [3] e3>e1>e2>e4 [4] e2>e3>e4>e1 61.In the following transition, which is correct [1] E3-1=E3-2-E2-1 [2] [3] U3=U2+U1 [4] All of the above 62.Which orbital is represented by wave function 310? [1] 3d [2] 3p [3] 3s [4] Data is insufficient 63.The set of quantum numbers for 19th electron of chromium (Z=24) is: [1] 4,0,0,+ [2] 4,1,-1,+ [3] 3,2,2,+ [4] 3,2,-2.+ 64.When principal quantum number n increases then the difference between two adjacent energy levels [1] Remain constant [2] Increases in Hydrogen atom will [3] Increases and decreases both [4] Decreases 65.For the atomic radius of the order of 10-8 cm and nuclear radius of the order of 10-13 cm.The fraction of atom occupied by the nucleus will be: [1]10-13 x atomic volume [2]10-14 x atomic volume [3]10-15 x atomic volume [4]10-16 x atomic volume 66.For a particular value of azimuthal quantum number the total number of magnetic quantum number value are given by [1] l= [2] l= [3] l= [4] l= 67.Which of the following have minimum Debroglie wave length [1] Electron [2] SO2 [3] CO2 [4] Proton 68.In the ground state of Cu2-,the number of shells occupied ,subshells occupied,filled orbitals and unpaired electrons respectively are: [1] 4,8,15,0 [2] 3,6,15,1 [3] 3,6,14,1 [4] 4,7,14,1 69.Which one of the following will not form amphoteric oxide? [1] Al [2] Pb [3] Sn [4] Ba 70.Which of the following electronic configuration is correct for outer most orbit of Alkali metal [1] (n-1)s2,p2,ns2p1 [2] (n-1)s2p2d10,ns1 [3] (n-1)s2 p6,ns1 [4] ns2p6d1 71.Correct order of Electronegativity is- [1] O+>O>O- [2] O>O+>O- [3] O+>O->O [4] O->O>O+ 72. The chloride of an element A given neutral solution in Water.The element A belongs to the group- [1] First Group [2] Third Group [3] Fifth Group [4] First Transition Series 73.Correct order of b.p. is- [1]CO2<>2<>4<>2O [2]H2O<>4<>2<>2 [3]CS2<>2<>4<>2O [4]H2O<>2<>2<>4 74.Which of the following have maximum difference in radius [1] Cr,Mn [2] Co,Ni [3] K,Ca [4] Mn,Fe 75.Which of the following has maximum density- [1] Pb [2] Hg [3] Ir [4] Os 76.Which one is most stable:- [1] H [2] H+ [3] H2+ [4] H- 77.Which one is strongest reducing ion? [1] F- [2] Cl- [3] Br- [4] I- 78.Hydration energy of Mg2+ is greater than the Hydration energy of [1] Be2+ [2] Na+ [3] Al3+ [4] Cr3+ 79.Which of the following has maximum non metallic Character? [1] Be [2] B [3] Mg [4] Al 80.The correct order of increasing electronegativity is? [1] P [2] Cl [3] Bi [4] S 81.Which concept best explains the fact the o-nitrophenol is more volatile than p-nitrophenol? [1] Resonance [2] Hyperconjugation [3] Hydrogen bonding [4] Setric hindrance 82.Bond order of NOmolecule is :- [1] 1 [2] 2 [3] 3 [4] 2.5 83.Sugar solution in water have [1] Free molecules [2] Free atoms [3] Free Ions [4] (a) and (b) both 84.Which one of the following has positive dipole Moment? [1] CCl4 [2] C6H6 [3] BF3 [4] HF 85. In [Cu(NH3)4]SO4,Hybridization of Cu is:- [1] dsp2 [2] sp3d2 [3] sp2 [4] sp3 86.In CH3COCl,the orbital used for bond formation by the carbon which is surrounded,is [1] sp [2] sp2 [3] sp3 [4] sp3d 87.Hydrogen bond is not present in- [1] Glycerine [2] water [3] H2S [4] HF 88.Which of the following has pyramidal shape? [1] NO3- [2] H2O [3] H3O+ [4] NH4+ 89.Resonance hybrid of Nitrate ion is :- [1] [2] [3] [4] 90.Electronic formula of COCl2 is :- [1] [2] [3] [4] None of these 91.Which of the following species contain covalent and co-ordinate bonds? [1] N2H5+ [2] BaCl2 [3] H2O [4] HCl 92.Which one has maximum boiling point :- [1] Acetone [2] Diethyl Ether [3] Chloroform [4] Ethyl Alcohol 93.Correct decreasing order of Bond Angle in following Hydrides is :- [1] NH3>PH3>AsH3>SbH3 [2]NH3>AsH3>SbH3>PH3 [3]PH3>NH3>AsH3>SbH3 [4]SbH3>AsH3>PH3>NH3 94.Which have unpaired electron in KO2,AlO2-,BaO2 and NO2+ [1] KO2 and AlO2- [2] NO2+ and BaO2 [3] Only BaO2 [4] Only KO2 95.N2 is less reactive than CN- due to [1] More electron in orbitals [2] difference in spin quantum number [3] Absence of dipole moment [4] None of these 96. Which one has maximum melting point :- [1] Alkali metal [2] Alkaline earth metal [3] Transition metals [4] All have equal 97.In the following which one is Lewis Acid:- [1] BF3 [2] NH3 [3] H2O [4] R-O-R 98.Increasing order of bond strength in O2,O2-O22- and O2+ is - [1] O2+<>2<>2-<>22- [2]O2<>2+<>2-<>22- [3]O2-<>22-<>2+<>2 [4]O22-<>2-<>2<>2+ 99.Which of the following molecules has maximum C-C atomic distance :- [1] C2H6 [2] C2H4 [3] C2H2 [4] C6H6 100.Which one of the following is soluble in water? [1] CCl4 [2] CS2 [3] CHCl3 [4] C2H5OH

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